Publications Inverse Axial-Ligand Effects in the Activation of H2O2 and ROOH by a Mn(III) Corrolazine Lansky, D.E.; Sarjeant, A.; Goldberg*, D.P.; Angew. Chem. 2006, Published Online Nov 14, 2006. A Low-Spin Alkylperoxo-Iron(III) Complex with weak Fe-O and O-O Bonds: Implications for the Mechanism of Superoxide Reductase Krishnamurthy, D.; Kasper, G.D.; Namuswe, F.; Kerber, W.D.; Sarjeant, A.; Moenne-Loccoz, P.; Goldberg*, D.P.; J. Am. Chem. Soc. 2006, 128, 14222- 14223. An Isolable, Nonreducible High-Valent Manganese(V) Imido Corrolazine Complex Lansky, D.E.; Kosack, J.R.; Sarjeant, A.; Goldberg*, D.P.; Inorg. Chem. 2006, 45, 8477-8479. Hydrogen Atom Abstraction by a High-Valent Manganse(V)-Oxo Corrolazine Lansky, D.E.; Goldberg*, D.P.; Inorg. Chem. 2006, 45, 5119-5125. A Combinatorial Approach to Minimal Peptide Models of a Metalloprotein Active Site Namuswe, F.; Goldberg*, D.P.; Chem. Comm. 2006, 2326-2328. High-Valent Transition Metal Corrolazines Kerber, W. D.; Goldberg*, D.P.; J. Inorg. Biochem. 2006, 100, 838-857. Geometric Preferences in Iron(II) and Zinc(II) Model Complexes of Peptide Deformylase Karambelkar, V.V.; Xiao, C.; Zhang, Y.; Sarjeant, A.A.N.; Goldberg*, D.P.; Inorg. Chem. 2006, 45, 1409-1411. Phosphate Triester Hydrolysis Promoted by an N2S(thiolate)Zinc Complex: Mechanistic Implications for the Metal-Dependent Reactivity of Peptide Deformylase Goldberg*, D.P.; diTargiani, R.C.; Namuswe, F.; Minnihan, E.C.; Chang, S.; Zakharov, L.N.; Rheingold, A.L.; Inorg. Chem. 2005, 44, 7559-7569.
Mononuclear, Dinuclear, and Pentanuclear (N,S(thiolate))Iron(II) Complexes: Nuclearity Control, Incorporation of Hydroxide Bridging Ligands, and Magnetic Behavior Krishnamurthy, D.; Sarjeant, A.; Goldberg*, D.P.; Caneschi, A.; Totti, F.; Zakharov, L.N.; Rheingold, A.L.; Chemistry: A European Journal, 2005, 11(24), 7328-7341. Synthesis, Characterization, and Physiochemical Properties of Manganese(III) and Manganese(V)-Oxo Corrolazines Lansky, D.E.; Mandimutsira, B.; Ramdhanie, B.; Clausen, M.; Penner-Hahn, J.; Zvyagin, S.A.; Telser, J.; Krzystek, J.; Zhan, R.; Zhongping, O.; Kadish*, K.M.; Zhakarov, L.; Rheingold, A.L.; Goldberg*, D.P.; Inorg. Chem., 2005, 44, 4485-4498. Recent Advances in the Chemistry of Corroles and Core-Modified Corroles Gryko, D.T.; Fox, J.P.; Goldberg*, D.P.; J. Porphyrins Phthalocyanines 2004; 8; 1091-1105. Catalytic Sulfoxidation and Epoxidation with a Mn(III) Triazacorrole: Evidence for A "Third Oxidant" in High-Valent Porphyrinoid Oxidations Wang, S. H.; Mandimutsira, B. S.; Todd, R.; Ramdhanie, B.; Fox, J. P.; Goldberg*, D. P.; J. Am. Chem. Soc.; 2004; 126(1); 18-19. Copper(III) and Vanadium(IV)-Oxo Corrolazines Fox, J. P.; Ramdhanie, B.; Zareba, A. A.; Czernuszewicz, R. S.; Goldberg*, D. P.; Inorg. Chem.; 2004; 43(21); 6600-6608. An Example of O2 Binding in a Cobalt(II) Corrole System and High-Valent Cobalt-Cyano and Cobalt-Alkynyl Complexes Ramdhanie, B.; Telser, J.; Caneschi, A.; Zakharov, L. N.; Rheingold, A. L.; Goldberg*, D. P.; J. Am. Chem. Soc.; 2004; 126(8); 2515-2525. Multiple bonding modes exhibited by heteroscorpionate N2S(alkylthiolate) ligands with Zn(II) and Fe(II) Karambelkar, V.V.; diTargiani, R.C.; Incarvito, C.D.; Zakharov, L.N.; Rheingold, A.L.; Stern, C.L.; Goldberg*, D.P.; Polyhedron; 2004; 23(2-3), 471-480. Octalkoxy-Substituted Phosphorus(V)Triazatetrabenzcorroles via Ring Contraction of Phthalocyanine Precursors Fox, J. P.; Goldberg*, D. P.; Inorg. Chem.; 2003; 42(25); 8181-8191. Hydrolysis of 4-Nitrophenyl Acetate by a (N2S(thiolate))zinc Hydroxide Complex: A Model of the Catalytically Active Intermediate for the Zinc Form of Peptide Deformylase diTargiani, R. C.; Chang, S.; Salter, M. H., Jr.; Hancock, R. D.; Goldberg*, D. P.; Inorg. Chem.; 2003; 42(19); 5825-5836. A Stable Manganese(V)-Oxo Corrolazine Complex Mandimutsira, B. S.; Ramdhanie, B.; Todd, R. C.; Wang, H.; Zareba, A. A.; Czernuszewicz, R. S.; Goldberg*, D. P.; J. Am. Chem. Soc.; 2002; 124(51); 15170-15171. Synthesis, Structures, and Properties of a Series of Four-, Five-, and Six-Coordinate Cobalt(III) Triazacorrole Complexes: The First Examples of Transition Metal Corrolazines Ramdhanie, B.; Zakharov, L. N.; Rheingold, A. L.; Goldberg*, D. P.; Inorg. Chem.; 2002; 41(16); 4105-4107. New Monomeric Cobalt(II) and Zinc(II) Complexes of a Mixed N,S(alkylthiolate) Ligand: Model Complexes of (His)(His)(Cys) Metalloprotein Active Sites Chang, S.; Karambelkar, V. V.; Sommer, R. D.; Rheingold, A. L.; Goldberg*, D. P.; Inorg. Chem.; 2002; 41(2); 239-248. A New Bis(imidazolyl)(alkylthiolate) Tripodal Ligand and the Spontaneous Formation of a Disulfide-Linked, Hydroxo-Bridged Dinuclear Zinc Complex Karambelkar, V.K.; Krishnamurthy, D.; Stern, C.L.; Zakharov, L.N.; Rheingold, A.L.; Goldberg*, D.P.; Chem. Commun.; 2002; 2772-2773. Synthesis of the First Corrolazine: A New Member of the Porphyrinoid Family Ramdhanie, B.; Stern, C. L.; Goldberg*, D. P.; J. Am. Chem. Soc.; 2001; 123(38); 9447-9448. Model Complexes of the Active Site in Peptide Deformylase: A New Family of Mononuclear N2S-M(II) Complexes Chang, S.; Karambelkar, V. V.; diTargiani, R. C.; Goldberg*, D. P.; Inorg. Chem.; 2001; 40(2); 194-195. A model complex of a possible intermediate in the mechanism of action of peptide deformylase: first example of an (N2S)zinc(II) formate complex Chang, S.; Sommer, R.D.; Rheingold, A.L.; Goldberg*, D.P.; Chem. Commun.; 2001; 2396-2397. High-Frequency and –Field Electron Paramagnetic Resonance of High-Spin Manganese(III) in Tetrapyrrole Complexes Krzystek, J.; Pardi, L. A.; Brunel, L.-C.; Goldberg, D. P.; Hoffman*, B. M.; Licoccia, S.; Telser, J.; Spectrochim. Acta, Pt. A, 2002, 1113-1127. High-Frequency and –Field Electron Paramagnetic Resonance of High-Spin Manganese(III) in Porphyrinic Complexes Krzystek, J.; Telser, J.; Pardi, L. A.; Goldberg, D. P.; Hoffman*, B. M.; Inorg. Chem., 1999, 6121-6129. Slow Magnetic Relaxation of [Et3NH]2[Mn(CH3CN)4(H2O)2][Mn10O4(biphen)4Br12] (biphen = 2,2’-biphenoxide) at Very Low Temperature Barra, A. L.; Caneschi, A.; Gatteschi, D.; Goldberg, D. P.; Sessoli*, R.J.; Solid State Chem., 1999, 484 - 487. Solitaire and Gemini Porphyrazines Michel, S. L. J.; Goldberg, D. P.; Stern, C.; Barrett, A. G. M.; Hoffman*, B. M.; J. Am. Chem. Soc., 2001, 123, 4741-4748. Metal Ion Binding to Octakis(dimethylamino)porphyrazine: Core Coordination of Mn(III) and Peripheral Coordination of Pd(II) Goldberg, D. P.; Montalban, A. G.; White A. J. P.; Williams, D. J.; Barrett A. G. M.; Hoffman*, B. M.; Inorg. Chem., 1998, 2873-2879. Molybdocene Porphyrazines: A Peripheral Dithiolene Metallacycle Fused to a Porphyrinic Core Goldberg, D. P.; Michel, S. L. J.; White, A. J. P.; Williams, D. J.; Barrett, A. G. M.; Hoffman*, B. M.; Inorg. Chem., 1998, 2100-2101. EPR Spectra from ‘EPR-Silent’ Species: High-Field EPR Spectroscopy of Manganese(III) Porphyrins Goldberg, D. P.; Telser, J.; Krzystek, J.; Montalban, A. G.; Brunel, L.-C.; Barrett, A. G. M.; Hoffman*, B. M.; J. Am. Chem. Soc., 1997, 8722-8723. A Decanuclear Manganese Cluster with Oxo and Halide Bridging Ligands: Magnetic Behavior of an S > 12 System Goldberg, D. P.; Caneschi, A.; Delfs, C.; Sessoli, R.; Lippard*, S. J.; J. Am. Chem. Soc., 1995, 5789-5800. A (µ-oxo)bis(µ-carboxylato)diiron(III) Complex with a Tethered Phenoxyl Radical as a Model for the Active Site of the R2 protein of Ribonucleotide Reductase Goldberg D. P.; Koulougliotis, D.; Brudvig, G. W.; Lippard*, S. J.; J. Am. Chem. Soc., 1995, 3134-3144. Ferromagnetic Versus Antiferromagnetic Exchange in Five Structurally Analogous Carboxylate-Bridged Trinuclear Ferrous Complexes Goldberg, D. P.; Telser, J.; Bastos; C. M.; Lippard*, S. J.; Inorg. Chem., 1995, 3011-3024. Modelling Phenoxyl Radical Metalloenzyme Active Sites Goldberg, D. P.; Lippard*, S. J.; In Mechanistic Bioinorganic Chemistry - Advances in Chemistry Series, Edited by H. H. Thorp and V. Pecoraro, 1995, vol. 246, pp. 61-81. Synthesis, Structure, and Magnetic Properties of Two Dinuclear Iron(III) Citrate Complexes Shweky, I.; Bino, A.; Goldberg, D. P.; Lippard*, S. J.; Inorg. Chem., 1994, 5161-5162. Methane Monooxygenase: Models and Mechanism Liu, K. E.; Feig, A. L.; Goldberg, D. P.; Watton, S. P.; Lippard*, S. J.; In The Activation of Dioxygen and Homogeneous Catalytic Oxidation, Edited by D. H. R. Barton et al., Plenum Press, New York, 1993, pp. 301-320. A Decanuclear Mixed-Valent Manganese Complex with A High Spin Multiplicity in the Ground State Goldberg, D. P.; Caneschi, A.; Lippard*, S. J.; J. Am. Chem. Soc., 1993, 9299-9300. Complexes of a Pendant Phenoxyl Radical Ligand, Including a New Model for the Ribonucleotide Reductase R2 Protein Goldberg, D. P.; Watton, S. P.; Masschelein, A.; Wimmer, L.; Lippard*, S. J.; J. Am. Chem. Soc., 1993, 5346-5347. Synthesis and Characterization of Trinuclear Iron(II) and Manganese(II) Carboxylate Complexes: Structural Trends in Low Valent Iron and Manganese Carboxylates Rardin, R. L.; Poganiuch, P.; Bino, A.; Goldberg, D. P.; Tolman, W. B.; Liu, S.; Lippard*, S. J.; J. Am. Chem. Soc., 1992, 5240-5249.
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