Ball and stick models of molecules
Johns Hopkins University logoDepartment of Chemistry

Goldberg Group Home

Research

Publications

David Goldberg

Group Members

Lab Photos

Teaching

High School Outreach

Chemistry Department

Directions


Stockroom Order

NMR Login

X-Ray

Sheridan Library

Hopkins Messaging

NMR (SDBS)

Mass Spec

Search Chemistry:

JHU Department of Chemistry
137 Remsen Hall
3400 N. Charles Street
Baltimore, MD 21218

410-516-7429 phone
410-516-8420 fax

Publications

Inverse Axial-Ligand Effects in the Activation of H2O2 and ROOH by a Mn(III) Corrolazine
Lansky, D.E.; Sarjeant, A.; Goldberg*, D.P.; Angew. Chem. 2006, Published Online Nov 14, 2006.

A Low-Spin Alkylperoxo-Iron(III) Complex with weak Fe-O and O-O Bonds: Implications for the Mechanism of Superoxide Reductase
Krishnamurthy, D.; Kasper, G.D.; Namuswe, F.; Kerber, W.D.; Sarjeant, A.; Moenne-Loccoz, P.; Goldberg*, D.P.;  J. Am. Chem. Soc. 2006, 128, 14222- 14223.

An Isolable, Nonreducible High-Valent Manganese(V) Imido Corrolazine Complex
Lansky, D.E.; Kosack, J.R.; Sarjeant, A.; Goldberg*, D.P.; Inorg. Chem. 2006, 45, 8477-8479.

Hydrogen Atom Abstraction by a High-Valent Manganse(V)-Oxo Corrolazine
Lansky, D.E.; Goldberg*, D.P.; Inorg. Chem. 2006, 45, 5119-5125.

A Combinatorial Approach to Minimal Peptide Models of a Metalloprotein Active Site
Namuswe, F.; Goldberg*, D.P.; Chem. Comm. 2006, 2326-2328.

High-Valent Transition Metal Corrolazines
Kerber, W. D.; Goldberg*, D.P.; J. Inorg. Biochem. 2006, 100, 838-857.

Geometric Preferences in Iron(II) and Zinc(II) Model Complexes of Peptide Deformylase
Karambelkar, V.V.; Xiao, C.; Zhang, Y.; Sarjeant, A.A.N.; Goldberg*, D.P.; Inorg. Chem. 2006, 45, 1409-1411.

Phosphate Triester Hydrolysis Promoted by an N2S(thiolate)Zinc Complex: Mechanistic Implications for the Metal-Dependent Reactivity of Peptide Deformylase
Goldberg*, D.P.; diTargiani, R.C.; Namuswe, F.; Minnihan, E.C.; Chang, S.; Zakharov, L.N.; Rheingold, A.L.; Inorg. Chem. 2005, 44, 7559-7569.

Mononuclear, Dinuclear, and Pentanuclear (N,S(thiolate))Iron(II) Complexes: Nuclearity Control, Incorporation of Hydroxide Bridging Ligands, and Magnetic Behavior
Krishnamurthy, D.; Sarjeant, A.; Goldberg*, D.P.; Caneschi, A.; Totti, F.; Zakharov, L.N.; Rheingold, A.L.; Chemistry: A European Journal, 2005, 11(24), 7328-7341.

Synthesis, Characterization, and Physiochemical Properties of Manganese(III) and Manganese(V)-Oxo Corrolazines
Lansky, D.E.; Mandimutsira, B.; Ramdhanie, B.; Clausen, M.; Penner-Hahn, J.; Zvyagin, S.A.; Telser, J.; Krzystek, J.; Zhan, R.; Zhongping, O.; Kadish*, K.M.; Zhakarov, L.; Rheingold, A.L.; Goldberg*, D.P.; Inorg. Chem., 2005,
44, 4485-4498.

Recent Advances in the Chemistry of Corroles and Core-Modified Corroles
Gryko, D.T.; Fox, J.P.; Goldberg*, D.P.; J. Porphyrins Phthalocyanines 2004; 8; 1091-1105.

Catalytic Sulfoxidation and Epoxidation with a Mn(III) Triazacorrole: Evidence for A "Third Oxidant" in High-Valent Porphyrinoid Oxidations
Wang, S. H.; Mandimutsira, B. S.; Todd, R.; Ramdhanie, B.; Fox, J. P.; Goldberg*, D. P.; J. Am. Chem. Soc.; 2004; 126(1); 18-19. 

Copper(III) and Vanadium(IV)-Oxo Corrolazines
Fox, J. P.; Ramdhanie, B.; Zareba, A. A.; Czernuszewicz, R. S.; Goldberg*, D. P.; Inorg. Chem.; 2004; 43(21); 6600-6608.

An Example of O2 Binding in a Cobalt(II) Corrole System and High-Valent Cobalt-Cyano and Cobalt-Alkynyl Complexes
Ramdhanie, B.; Telser, J.; Caneschi, A.; Zakharov, L. N.; Rheingold, A. L.; Goldberg*, D. P.; J. Am. Chem. Soc.; 2004; 126(8); 2515-2525.

Multiple bonding modes exhibited by heteroscorpionate N2S(alkylthiolate) ligands with Zn(II) and Fe(II) 
Karambelkar, V.V.; diTargiani, R.C.; Incarvito, C.D.; Zakharov, L.N.; Rheingold, A.L.; Stern, C.L.; Goldberg*, D.P.;
Polyhedron; 2004; 23(2-3), 471-480.

Octalkoxy-Substituted Phosphorus(V)Triazatetrabenzcorroles via Ring Contraction of Phthalocyanine Precursors
Fox, J. P.; Goldberg*, D. P.; Inorg. Chem.; 2003; 42(25); 8181-8191.

Hydrolysis of 4-Nitrophenyl Acetate by a (N2S(thiolate))zinc Hydroxide Complex: A Model of the Catalytically Active Intermediate for the Zinc Form of Peptide Deformylase
diTargiani, R. C.; Chang, S.; Salter, M. H., Jr.; Hancock, R. D.; Goldberg*, D. P.; Inorg. Chem.; 2003; 42(19); 5825-5836.

A Stable Manganese(V)-Oxo Corrolazine Complex
Mandimutsira, B. S.; Ramdhanie, B.; Todd, R. C.; Wang, H.; Zareba, A. A.; Czernuszewicz, R. S.; Goldberg*, D. P.; J. Am. Chem. Soc.; 2002; 124(51); 15170-15171.

Synthesis, Structures, and Properties of a Series of Four-, Five-, and Six-Coordinate Cobalt(III) Triazacorrole Complexes: The First Examples of Transition Metal Corrolazines
Ramdhanie, B.; Zakharov, L. N.; Rheingold, A. L.; Goldberg*, D. P.; Inorg. Chem.; 2002; 41(16); 4105-4107.

New Monomeric Cobalt(II) and Zinc(II) Complexes of a Mixed N,S(alkylthiolate) Ligand: Model Complexes of (His)(His)(Cys) Metalloprotein Active Sites
Chang, S.; Karambelkar, V. V.; Sommer, R. D.; Rheingold, A. L.; Goldberg*, D. P.; Inorg. Chem.; 2002; 41(2); 239-248.

A New Bis(imidazolyl)(alkylthiolate) Tripodal Ligand and the Spontaneous Formation of a Disulfide-Linked, Hydroxo-Bridged Dinuclear Zinc Complex
Karambelkar, V.K.; Krishnamurthy, D.; Stern, C.L.; Zakharov, L.N.; Rheingold, A.L.; Goldberg*, D.P.; Chem. Commun.; 2002; 2772-2773.

Synthesis of the First Corrolazine: A New Member of the Porphyrinoid Family
Ramdhanie, B.; Stern, C. L.; Goldberg*, D. P.; J. Am. Chem. Soc.; 2001; 123(38); 9447-9448.

Model Complexes of the Active Site in Peptide Deformylase: A New Family of Mononuclear N2S-M(II) Complexes
Chang, S.; Karambelkar, V. V.; diTargiani, R. C.; Goldberg*, D. P.; Inorg. Chem.; 2001; 40(2); 194-195.

A model complex of a possible intermediate in the mechanism of action of peptide deformylase: first example of an (N2S)zinc(II) formate complex
Chang, S.; Sommer, R.D.; Rheingold, A.L.; Goldberg*, D.P.; Chem. Commun.; 2001; 2396-2397.

High-Frequency and –Field Electron Paramagnetic Resonance of High-Spin Manganese(III)  in Tetrapyrrole Complexes
Krzystek, J.; Pardi, L. A.; Brunel, L.-C.; Goldberg, D. P.; Hoffman*, B. M.; Licoccia, S.; Telser, J.; Spectrochim. Acta, Pt. A,  2002, 1113-1127.

High-Frequency and –Field Electron Paramagnetic Resonance of High-Spin Manganese(III) in Porphyrinic Complexes
Krzystek, J.; Telser, J.; Pardi, L. A.; Goldberg, D. P.; Hoffman*, B. M.;
Inorg. Chem., 1999, 6121-6129.

Slow Magnetic Relaxation of [Et3NH]2[Mn(CH3CN)4(H2O)2][Mn10O4(biphen)4Br12] (biphen = 2,2’-biphenoxide) at Very Low Temperature
Barra, A. L.; Caneschi, A.; Gatteschi, D.; Goldberg, D. P.; Sessoli*, R.J.; Solid State Chem., 1999, 484 - 487.

Solitaire and Gemini Porphyrazines
Michel, S. L. J.; Goldberg, D. P.; Stern, C.; Barrett, A. G. M.; Hoffman*, B. M.;  
J. Am. Chem. Soc., 2001, 123, 4741-4748.

Metal Ion Binding to Octakis(dimethylamino)porphyrazine:  Core Coordination of Mn(III) and Peripheral Coordination of Pd(II)
Goldberg, D. P.; Montalban, A. G.; White A. J. P.; Williams, D. J.; Barrett A. G. M.; Hoffman*, B. M.;
Inorg. Chem., 1998, 2873-2879.

Molybdocene Porphyrazines:  A Peripheral Dithiolene Metallacycle Fused to a Porphyrinic Core
Goldberg, D. P.; Michel, S. L. J.; White, A. J. P.; Williams, D. J.; Barrett, A. G. M.; Hoffman*, B. M.;  
Inorg. Chem., 1998, 2100-2101.

EPR Spectra from ‘EPR-Silent’ Species:  High-Field EPR Spectroscopy of Manganese(III) Porphyrins 
Goldberg, D. P.; Telser, J.; Krzystek, J.; Montalban, A. G.; Brunel, L.-C.; Barrett, A. G. M.; Hoffman*, B. M.;
 J. Am. Chem. Soc., 1997, 8722-8723.

A Decanuclear Manganese Cluster with Oxo and Halide Bridging Ligands:  Magnetic Behavior of an S > 12 System
Goldberg, D. P.; Caneschi, A.; Delfs, C.; Sessoli, R.; Lippard*, S. J.;  
J. Am. Chem. Soc., 1995, 5789-5800.

A (µ-oxo)bis(µ-carboxylato)diiron(III) Complex with a Tethered Phenoxyl Radical as a Model for the Active Site of the R2 protein of Ribonucleotide Reductase
Goldberg D. P.; Koulougliotis, D.; Brudvig, G. W.; Lippard*, S. J.;  
J. Am. Chem. Soc., 1995, 3134-3144.

Ferromagnetic Versus Antiferromagnetic Exchange in Five Structurally Analogous Carboxylate-Bridged Trinuclear Ferrous Complexes 
Goldberg, D. P.; Telser, J.; Bastos; C. M.; Lippard*, S. J.; 
Inorg. Chem., 1995, 3011-3024.

Modelling Phenoxyl Radical Metalloenzyme Active Sites 
Goldberg, D. P.; Lippard*, S. J.;
In Mechanistic Bioinorganic Chemistry - Advances in Chemistry Series, Edited by H. H. Thorp and V. Pecoraro, 1995, vol. 246, pp. 61-81.

Synthesis, Structure, and Magnetic Properties of Two Dinuclear Iron(III) Citrate Complexes
Shweky, I.; Bino, A.; Goldberg, D. P.; Lippard*, S. J.; 
Inorg. Chem., 1994, 5161-5162.

Methane Monooxygenase: Models and Mechanism 
Liu, K. E.; Feig, A. L.; Goldberg, D. P.; Watton, S. P.; Lippard*, S. J.;
In The Activation of Dioxygen and Homogeneous Catalytic Oxidation, Edited by D. H. R. Barton et al., Plenum Press, New York, 1993, pp. 301-320.

A Decanuclear Mixed-Valent Manganese Complex with  A High Spin Multiplicity in the Ground State
Goldberg, D. P.; Caneschi, A.; Lippard*, S. J.
J. Am. Chem. Soc., 1993, 9299-9300.

Complexes of a Pendant Phenoxyl Radical Ligand, Including a New Model for the Ribonucleotide Reductase R2 Protein 
Goldberg, D. P.; Watton, S. P.; Masschelein, A.; Wimmer, L.; Lippard*, S. J.;
J. Am. Chem. Soc., 1993, 5346-5347.

Synthesis and Characterization of Trinuclear Iron(II) and Manganese(II) Carboxylate Complexes:  Structural Trends in Low Valent Iron and Manganese Carboxylates
Rardin, R. L.; Poganiuch, P.; Bino, A.; Goldberg, D. P.; Tolman, W. B.; Liu, S.; Lippard*, S. J.
J. Am. Chem. Soc., 1992, 5240-5249.


 

Group Home | ResearchPublicationsDavid Goldberg |Group Members  Lab Photos | Teaching |Chemistry